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I am not really sure why I never watched the show when it started in 2007. I do know that I did not yet have DVR, so I was probably watching How I Met Your Mother instead. I actually do not really remember thinking about it much when it was on. I loved Adam Baldwin in Firefly and Sarah Lancaster in What About Brian (also, Saved By The Bell: The New Class...shhh), and probably recognized Zachary Levi, but none of them were enough to interest me in the show. This was also about the time that I was *not* watching Friday Night Lights either so, clearly, I was not thinking straight.
To be honest, the reason I did start watching Chuck was because of Orphan Black. I know that sounds weird, so let me explain. As I have mentioned before, I watched all of Orphan Black after last year's ATX Television Festival and was instantly obsessed. Shortly after watching the whole first season, the cast went to San Diego Comic Con, at which they did a panel for Zachary Levi's Nerd Machine. Once I discovered the Orphan Black panel online, I then watched many of the other Nerd Machine panels throughout the weekend that were streaming on YouTube, including one with Levi himself, and soon came to the conclusion that I should at least give Chuck a try.
The only way that I could watch it initially was to get the discs from Netflix, so the first two seasons took me quite a while to get through. (And when I say, "quite a while," I mean about two months.) I was just starting to lose steam and then, as if they knew exactly what I was thinking, Netflix made the whole series available to stream the following week and I flew threw the last three seasons.